Superatom Lab

Dedicated to study the chemistry and physics of superatomic clusters and nanoscale systems to solve pressing issues in sustainable chemistry, environmental remediation, and clean energy.



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Rohul Hayat

Cluster and physical chemist





Superatom Lab

Dedicated to study the chemistry and physics of superatomic clusters and nanoscale systems to solve pressing issues in sustainable chemistry, environmental remediation, and clean energy.




Effect of Gold Nanoclusters on the Production of Ti3+ Defect Sites in Titanium Dioxide Nanoparticles under Ultraviolet and Soft X-ray Radiation


Journal article


T. Bennett, R. H. Adnan, J. F. Alvino, R. Kler, V. Golovko, G. Metha, G. Andersson
Journal of Physical Chemistry C, 2015, p. 11171


Semantic Scholar DOI
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Cite

APA   Click to copy
Bennett, T., Adnan, R. H., Alvino, J. F., Kler, R., Golovko, V., Metha, G., & Andersson, G. (2015). Effect of Gold Nanoclusters on the Production of Ti3+ Defect Sites in Titanium Dioxide Nanoparticles under Ultraviolet and Soft X-ray Radiation. Journal of Physical Chemistry C, 11171. https://doi.org/10.1021/jp5119162


Chicago/Turabian   Click to copy
Bennett, T., R. H. Adnan, J. F. Alvino, R. Kler, V. Golovko, G. Metha, and G. Andersson. “Effect of Gold Nanoclusters on the Production of Ti3+ Defect Sites in Titanium Dioxide Nanoparticles under Ultraviolet and Soft X-Ray Radiation.” Journal of Physical Chemistry C (2015): 11171.


MLA   Click to copy
Bennett, T., et al. “Effect of Gold Nanoclusters on the Production of Ti3+ Defect Sites in Titanium Dioxide Nanoparticles under Ultraviolet and Soft X-Ray Radiation.” Journal of Physical Chemistry C, 2015, p. 11171, doi:10.1021/jp5119162.


BibTeX   Click to copy

@article{t2015a,
  title = {Effect of Gold Nanoclusters on the Production of Ti3+ Defect Sites in Titanium Dioxide Nanoparticles under Ultraviolet and Soft X-ray Radiation},
  year = {2015},
  journal = {Journal of Physical Chemistry C},
  pages = {11171},
  doi = {10.1021/jp5119162},
  author = {Bennett, T. and Adnan, R. H. and Alvino, J. F. and Kler, R. and Golovko, V. and Metha, G. and Andersson, G.}
}

Abstract

The production rate and saturation point of Ti3+ defect sites on titanium dioxide P-25 and anatase nanoparticles doped with Au101(PPh3)21Cl5 (Au101) metal nanoclusters were investigated under synchrotron X-ray irradiation alone, as well as combined X-ray and UV radiation. The saturation point in the growth of the normalized relative populations of Ti3+ centers on anatase and P-25 titania nanoparticles with and without Au101 nanoclusters present at the surface was found to vary with the type of support. It was influenced by the presence of gold nanoclusters: a higher concentration of Ti3+ centers was generated where gold nanoclusters were deposited onto anatase nanoparticles and irradiated by both X-ray and UV photons, compared with X-ray irradiation alone. Conversely, all samples based on the TiO2 P-25 support displayed reduced levels of Ti3+ center populations at the saturation points under combined X-ray and UV combined radiation, compared to the samples exposed exclusively to X-ray radiation. The initi...


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